PermeOx® Plus in Remediation Treatments

 In the environmental industry, the use of amendments for soil and groundwater cleanup is increasing in acceptance. One very common practice is the use of aerobic microbes to degrade hydrocarbon contaminants.  Nutrients and oxygen are supplied to the microbes to enhance this natural process.

 FMC introduces a solid, controlled released calcium peroxide formulation under the name PermeOx® Plus for environmental applications.  The low solubility of PermeOx® Plus provides a slow release of oxygen.  As a solid, it is ideal for use in bioremediation technologies such as land farming, biotreatment cells and multiple lift soil systems.  Typically, PermeOx® Plus is blended into the soil along with the nutrients during initial soil preparation.

 Laboratory research and field applications experience have shown that PermeOx® Plus can speed up the bioremediation process and may offer lower treatment costs compared to other remediation methods.

 PermeOx® Plus Chemistry

 Soil moisture and pH trigger a gradual release of oxygen, after adding PermeOx® Plus. This oxygen release proceeds stepwise, starting with formation of hydrogen peroxide and calcium hydroxide.  The hydrogen peroxide then decomposes to form oxygen and water.

 PermeOx® Plus is yellow to off- white, dry, flow able granular material that contains minimum 75 percent calcium peroxide and has active oxygen content of 17 percent (minimum by weight), versus 8 to 10 percent for magnesium peroxide. The remaining 25 percent is primarily made up of calcium oxide, calcium hydroxide and bound water.

 Field experience has shown that PermeOx® Plus offers substantial benefits in the following situations:

 

     When soil cleanups must be completed within specific time guidelines to facilitate site closure, or when limited space demands faster treatment and soil removal.

•    In land farming where operators wish to reduce the frequency of tilling to save operating costs (fuel, equipment, and manpower) and minimize release of volatile organic compounds.

    In heavy clay soils where PermeOx® Plus not only provides a source of oxygen, but helps improve hydraulic conductivity, permitting more efficient movement of nutrients and oxygen through the soil.

     In remote locations where daily or weekly site maintenance and monitoring is not practical, or other means of oxygen supply are not readily available.

 

In pilot tests at EPA Superfund site, PermeOx® Plus treated soils showed increased total microbial populations and the species diversity when compared to control and tilled plots.  Increasing species diversity suggests the ability to degrade a wider range of chemical contaminants.

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